|
|
arachidoyl-CoA + O2 + ferricytochrome_b5 + H+ <=> (Z)-icos-5-enoyl-CoA + H2O + ferricytochrome_b5
|
1.14.19.10
icosanoyl-CoA 5-desaturase
|
–
|
M
|
|
BRENDA:
BR51299
KEGG:
R10926
MetaCyc:
RXN-8372
|
|
|
|
arachidoyl-CoA + NADP+ <=> (2E)-eicosenoyl-CoA + NADPH + H+
|
1.3.1.8
acyl-CoA dehydrogenase (NADP+)
1.3.1.93
very-long-chain enoyl-CoA reductase
|
–
–
|
M
|
|
BRENDA:
BS258628
MetaCyc:
RXN-13306
|
|
|
|
arachidoyl-CoA + Dodecanol <=> Dodecanyl_eicosanoate + CoA
|
2.3.1.75
long-chain-alcohol O-fatty-acyltransferase
|
–
|
|
|
BRENDA:
BS321298
MetaCyc:
RXN-9356
|
|
|
|
arachidoyl-CoA + H2O <=> eicosanoic_acid + CoA + H+
|
3.1.2.2
palmitoyl-CoA hydrolase
3.1.2.20
acyl-CoA hydrolase
|
–
–
|
K
|
|
BRENDA:
BS360751
KEGG:
R08175
MetaCyc:
RXN-9629
SABIO-RK:
6594
|
|
|
|
arachidoyl-CoA + sphinganine <=> N-arachidoylsphinganine + CoA + H+
|
2.3.1.24
sphingosine N-acyltransferase
2.3.1.297
very-long-chain ceramide synthase
2.3.1.M71
|
–
–
–
|
|
|
BRENDA:
BS448947
MetaCyc:
RXN-20370
|
|
|
|
stearoyl-CoA + malonyl-CoA + 2 NADPH + 2 H+ <=> arachidoyl-CoA + CO2 + 2 NADP+ + CoA + H2O
|
not assigned
|
–
|
|
|
KEGG:
R02224
|
|
|
|
arachidoyl-CoA + 4 methylmalonyl-CoA + 8 NADPH + 8 H+ + [acyl-carrier_protein] <=> C32-Mycocerosyl-[acp] + 5 CoA + 4 CO2 + 8 NADP+ + 4 H2O
|
2.3.1.111
mycocerosate synthase
|
–
|
|
|
KEGG:
R11450
|
|
|
|
malonyl-CoA + arachidoyl-CoA + H+ <=> 3-oxobehenoyl-CoA + CO2 + CoA
|
2.3.1.199
very-long-chain 3-oxoacyl-CoA synthase
|
–
|
M
|
|
MetaCyc:
RXN-13295
|
|
|
|
arachidoyl-CoA + (S)-methylmalonyl-CoA + NADPH + H+ + holo_mycolipanoate_synthase <=> C29-mycolipanoyl-[mycolipanoate_synthase] + CoA + CO2 + NADP+ + H2O
|
2.3.1.252
mycolipanoate synthase
|
–
|
|
|
MetaCyc:
RXN-17180
|
|
|
|
arachidoyl-[acp] + CoA <=> arachidoyl-CoA + [acyl-carrier_protein]
|
2.3.1
|
–
|
|
|
MetaCyc:
RXN1G-574
|
|
|
|
arachidoyl-CoA + hexadecanol <=> Hexadecanyl_eicosanoate + CoA
|
2.3.1.75
long-chain-alcohol O-fatty-acyltransferase
|
–
|
|
|
BRENDA:
BS321300
|
|
|
|
sphinganine + arachidoyl-CoA <=> N-arachidoyl-D-sphinganine + CoA
|
2.3.1.297
very-long-chain ceramide synthase
|
–
|
|
|
BRENDA:
BS448542
|
|
|
|
arachidoyl-CoA + sphinganine <=> CoA + N-arachidoyl-dihydrosphingosine
|
2.3.1.298
ultra-long-chain ceramide synthase
|
–
|
|
|
BRENDA:
BS449579
|
|
|
|
arachidoyl-CoA + sphinganine <=> N-(arachidoyl)-dihydrosphingosine + CoA
|
2.3.1.299
sphingoid base N-stearoyltransferase
|
–
|
|
|
BRENDA:
BS455325
|
|
|
|
arachidoyl-CoA + flavin <=> (2E)-eicosenoyl-CoA + reduced_flavodoxin
|
1.3.8.8
long-chain acyl-CoA dehydrogenase
|
–
|
|
|
BRENDA:
BS260357
|
|
|
|
arachidoyl-CoA + O2 <=> (2E)-eicosenoyl-CoA + H2O2
|
1.3.3.6
acyl-CoA oxidase
|
–
|
|
|
BRENDA:
BS258733
|
|
|
|
arachidoyl-CoA + docosanol <=> Docosanyl_eicosanoate + CoA
|
2.3.1.75
long-chain-alcohol O-fatty-acyltransferase
|
–
|
|
|
BRENDA:
BS321306
|
|
|
|
arachidoyl-CoA + cis-11-Eicosenol <=> cis-11-Eicosenyl_eicosanoate + CoA
|
2.3.1.75
long-chain-alcohol O-fatty-acyltransferase
|
–
|
|
|
BRENDA:
BS321305
|
|
|
|
arachidoyl-CoA + eicosanol <=> Eicosanyl_eicosanoate + CoA
|
2.3.1.75
long-chain-alcohol O-fatty-acyltransferase
|
–
|
|
|
BRENDA:
BS321303
|
|
|
|
arachidoyl-CoA + Decanol <=> Decanyl_eicosanoate + CoA
|
2.3.1.75
long-chain-alcohol O-fatty-acyltransferase
|
–
|
|
|
BRENDA:
BS321297
|
|
|
|
arachidoyl-CoA + 1-oleoyl-sn-glycerol_3-phosphate <=> CoA + 2-arachidoyl-1-oleoyl-sn-glycerol_3-phosphate
|
2.3.1.51
1-acylglycerol-3-phosphate O-acyltransferase
|
–
|
|
|
BRENDA:
BS444919
|
|
|
|
arachidoyl-CoA + sn-2-monooleoylglycerol <=> CoA + 1-arachidoyl-2-oleoylglycerol
|
2.3.1.22
2-acylglycerol O-acyltransferase
|
–
|
|
|
BRENDA:
BS320692
|
|
|
|
arachidoyl-CoA + oleyl_alcohol <=> cis-9-Octadecenyl_eicosanoate + CoA
|
2.3.1.75
long-chain-alcohol O-fatty-acyltransferase
|
–
|
|
|
BRENDA:
BS321302
|
|
|
|
arachidoyl-CoA + Tetradecanol <=> Tetradecanyl_eicosanoate + CoA
|
2.3.1.75
long-chain-alcohol O-fatty-acyltransferase
|
–
|
|
|
BRENDA:
BS321299
|
|
|
|
arachidoyl-CoA + octadecanol <=> Octadecanyl_eicosanoate + CoA
|
2.3.1.75
long-chain-alcohol O-fatty-acyltransferase
|
–
|
|
|
BRENDA:
BS321301
|
|
|
|
arachidoyl-CoA + cis-13-eicosenol <=> cis-13-Eicosenyl_eicosanoate + CoA
|
2.3.1.75
long-chain-alcohol O-fatty-acyltransferase
|
–
|
|
|
BRENDA:
BS321304
|
|
|
|
arachidoyl-CoA + 1-acyl-lysophosphatidic_acid <=> CoA + 1-acyl-2-arachidoyl-lysophosphatidic_acid
|
2.3.1.51
1-acylglycerol-3-phosphate O-acyltransferase
|
–
|
|
|
BRENDA:
BS455323
|
|
|
|
dihydroxyacetone_phosphate + arachidoyl-CoA <=> 1-arachidoyl-glycerone_phosphate + CoA
|
2.3.1.42
glycerone-phosphate O-acyltransferase
|
–
|
|
|
BRENDA:
BS388550
|
|
|
|
arachidoyl-CoA + L-carnitine <=> CoA + L-arachidoylcarnitine
|
2.3.1.21
carnitine O-palmitoyltransferase
|
–
|
|
|
BRENDA:
BS320677
|
|
|
|
arachidoyl-CoA + sn-glycerol_3-phosphate <=> CoA + 1-arachidonoyl-lysophosphatidic_acid
|
2.3.1.15
glycerol-3-phosphate 1-O-acyltransferase
|
–
|
|
|
BRENDA:
BS379180
|
|
|
|
arachidoyl-CoA + NADH <=> eicosanal + NAD+
|
1.2.1.42
hexadecanal dehydrogenase (acylating)
|
–
|
|
|
BRENDA:
BS189221-a
|
|
|
|
arachidoyl-CoA + sphingosine <=> arachidoyl_ceramide + CoA
|
2.3.1.298
ultra-long-chain ceramide synthase
|
–
|
|
|
BRENDA:
BS449580
|
|
|
|
sphingosine + arachidoyl-CoA <=> N-arachidoylsphingosine + CoA
|
2.3.1.297
very-long-chain ceramide synthase
|
–
|
|
|
BRENDA:
BS450648
|
|
|
|
sphingosine + arachidoyl-CoA <=> N-eicosanoylsphingosine + CoA
|
2.3.1.24
sphingosine N-acyltransferase
2.3.1.297
very-long-chain ceramide synthase
2.3.1.298
ultra-long-chain ceramide synthase
|
–
–
–
|
|
|
BRENDA:
BS448959
|
|
|
|
arachidoyl-CoA + NADPH + H+ <=> eicosanal + CoA + NADP+
|
1.2.1.50
long-chain acyl-protein thioester reductase
1.2.1.B25
|
–
–
|
|
|
BRENDA:
BS426505
|
|
|
|
arachidoyl-CoA + 4 methylmalonyl-CoA + 8 NADPH + 8 H+ <=> tetramethyl-branched_mycocerosoyl-CoA + 4 CoA + 4 CO2 + 8 NADP+ + 4 H2O
|
2.3.1.111
mycocerosate synthase
|
–
|
|
|
BRENDA:
BS320304
|
|
|
|
arachidoyl-CoA + 2 NADPH + 2 H+ <=> arachidol + 2 NADP+ + CoA
|
1.2.1.84
alcohol-forming fatty acyl-CoA reductase
|
–
|
|
|
BRENDA:
BS441056
|
|
|
|
arachidoyl-CoA + NADPH <=> eicosanal + NADP+
|
1.2.1.42
hexadecanal dehydrogenase (acylating)
|
–
|
|
|
BRENDA:
BS189215
|
|
|
|
arachidoyl-CoA + NADP+ <=> eicosanal + CoA + NADPH
|
1.2.1.50
long-chain acyl-protein thioester reductase
|
–
|
|
|
BRENDA:
BS372425
|
|
|
|
arachidoyl-CoA + malonyl-[acyl-carrier_protein] <=> 3-oxodocosanoyl-[acyl-carrier_protein] + CoA + CO2
|
2.3.1.180
beta-ketoacyl-[acyl-carrier-protein] synthase III
|
–
|
|
|
BRENDA:
BS381429
|
|
|
|
arachidoyl-CoA + phenazine_methosulfate <=> (2E)-eicosenoyl-CoA + reduced_phenazine_methosulfate
|
1.3.8.8
long-chain acyl-CoA dehydrogenase
|
–
|
|
|
BRENDA:
BS260369
|
|
|
|
arachidoyl-CoA + lysophosphatidic_acid <=> CoA + 1-acyl-2-arachidoyl-sn-glycerol_3-phosphate
|
2.3.1.51
1-acylglycerol-3-phosphate O-acyltransferase
|
–
|
|
|
BRENDA:
BS321045
|
|
|
|
arachidoyl-CoA + L-serine <=> CoA + 2-amino-1-hydroxydocosan-3-one + CO2
|
2.3.1.50
serine C-palmitoyltransferase
|
–
|
|
|
BRENDA:
BS321010
|
|
|
|
ATP + eicosanoic_acid + CoA <=> AMP + diphosphate + arachidoyl-CoA
|
6.2.1.3
long-chain-fatty-acid---CoA ligase
|
–
|
|
|
BRENDA:
BS443137
|
|